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21.
本文在文献[1]和[2]的基础上,将改进型三角形广义协调元TGC-9-1应用于薄板振动和稳定分析中。推导出带有一个内部自由度(外部结点有九个自由度)的三角形板单元的协调质量矩阵和几何刚度矩阵。并通过算例表明,改进型广义协调三角形单元(TGC-9-1)具有良好的性态和更好的精度,程序简便。 相似文献
22.
研究压电激励圆形曲梁的静态位移响应及位移控制的参数特性。将压电夹层圆形曲梁等效为单层结构,基于一维小曲率曲梁理论,建立其控制方程。在集中弯矩和径向集中力以及电载荷作用下,分析了带压电激励器的圆形悬臂曲梁的静态响应。与有限元结果比较表明:本文的理论模型能够模拟压电激励的小曲率圆形曲梁的静态响应。压电夹层圆形曲梁在任意位置的径向集中力载荷作用下,控制其自由端径向位移响应为零,求得控制电压的解析表达,数值分析表明:随着集中力载荷的位置变化和梁长的变化,最优控制电压将出现峰值和反号。 相似文献
23.
24.
Meiru Lu Dr. Xiaoling Wu Dr. Changlong Hao Prof. Chuanlai Xu Prof. Hua Kuang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(28):7023-7030
Nonylphenols (NPNs) are persistent endocrine disruptors and their release into the environment is causing increasing concern about their impact on human health. Herein, an ultrasensitive electrochemical immunosensor was developed for the detection of NPNs in the leachates from 61 instant noodle containers (INCs) from 8 countries across Southeast Asia. Gold nanoclusters (AuNCs) were self-assembled with reduced graphene oxide (rGO; polyethylenimine–rGO) and used to modify a glassy carbon electrode (GCE), which showed excellent electrical conductivity. An anti-NPN antibody was then immobilized on the AuNCs and, if it specifically bound NPN, the reduction in conductivity of the GCE was remarkable. The designed immunosensor has a low detection limit (5.25 ng L−1) and high sensitivity for NPNs in the leachates of INCs. Remarkably, the leaching of estrogen-like compounds from different plastics of INCs and the correlation between NPN content and total estrogenic activity were thoroughly investigated. High temperatures caused polyethylene and polystyrene INCs to release more estrogen-like compounds than that of polypropylene INCs; this increased release of NPNs was associated with higher estrogen activity in living cells. These data fill the gap in human and environmental exposure to estrogen-like compounds through INCs. 相似文献
25.
For a general quantum ensemble with Hamiltonian fluctuations, this paper proposes a sampling-based two-stage approximate time-optimal control algorithm with momentum terms and achieves a high-fidelity state transition of all member systems to a common target state within an approximate minimum time. The fidelity and the control time are respectively optimized in the two stages. In particular, the introduction of momentum terms greatly improves the convergence rate of the algorithm. Simulation experiments on a two-level quantum ensemble verify the effectiveness of the proposed algorithm. 相似文献
26.
Experimental and numerical investigation of aramid fibre reinforced laminates subjected to low velocity impact 总被引:1,自引:0,他引:1
The low velocity impact performance of domestic aramid fibre reinforced laminates is investigated experimentally and numerically. Laminates with different thicknesses are impacted by drop-weight test machine under different impact energies. The time histories of impact force are recorded and ultrasonic C-scan technology is used to inspect the internal damage of the laminates. Numerical simulation is conducted using finite element method (FEM), taking into account both intralaminar and interlaminar damage. The intralaminar damage model is based on the continuum damage mechanics (CDM) approach, which consists of the strain-based Hashin failure criteria and the exponential damage evolution law, and considers the nonlinear shear behaviour of the material. The interlaminar damage is simulated by interface elements with cohesive zone model. The numerical results show good agreements with the experiments, thus verifying the validity of the presented numerical model. 相似文献
27.
Dr. Gábor London Kuang‐Yen Chen Dr. Gregory T. Carroll Prof. Dr. Ben L. Feringa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(32):10690-10697
We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were introduced to the rotor part of the motors. Molecular motors were attached to quartz surfaces by using interfacial 1,3‐dipolar cycloadditions. To test the effect of the functional groups on the rotary motion, photochemical and thermal isomerization studies of the motors were performed both in solution and when attached to the surface. We found that the substituents have no significant effect on the thermal and photochemical processes, and the functionalized motors preserved their rotary function both in solution and on a quartz surface. Preliminary results on the influence of the functional groups on surface wettability are also described. 相似文献
28.
Xiang Hao Cuifang Kuang Yanghui Li Xu Liu Yulong Ku Yunshan Jiang 《Optics Communications》2012,285(20):4130-4133
By increasing the hydrophilicity of microsphere, the evaporation of liquid around the microsphere will be evidently eliminated, so that the droplet can remain stable, and it is more feasible to introduce the liquid immersed MMM system in practical utilizations that require long-time observation. Compared with the non-immersed one, the liquid immersed MMM system performs better in various aspects, and it is convenient to choose microspheres on a wider scale. 相似文献
29.
Dual template method to prepare hierarchical porous carbon nanofibers for high-power supercapacitors
Qiang Wang Qi Cao Xianyou Wang Bo Jing Hao Kuang Ling Zhou 《Journal of Solid State Electrochemistry》2013,17(10):2731-2739
Hierarchical porous carbon nanofibers serving as electrode materials are prepared through carbonization and hydrofluoric acid treatment of polyacrylonitrile-based electrospinning involving dual templates. The hierarchical porous structures are synergistically tailored by varying template contents in the spinning solution. The carbon nanofibers prepared from the electrospinning of polyacrylonitrile containing 15/15 wt.% polymethylmethacrylate/tetraethyl orthosilicate exhibit the largest specific surface area (699 m2 g?1) and microporous volume (0.196 cm3 g?1). In 6 M KOH electrolyte, a symmetrical supercapacitor equipped with the hierarchical porous carbon nanofibers demonstrates its high-end specific capacitance of 170 F g?1, superior rate capability, and high-power density output up to 14.7 kW kg?1. Cycling evolution indicates capacitance fading is only 5.8 % of initial capacitance at a current density of 1 A g?1 even after 8,000 cycles. The excellent electrochemical performances of the carbon nanofiber are mainly ascribed to the optimized pore size distributions of both micropores and mesopores and the unique hierarchical pore structures possessed by abundant micropores. 相似文献
30.
The reaction of the thiocarbamoyl‐molybdenum complex [Mo(CO)2(η2‐SCNMe2)(PPh3)2Cl] 1 , with EtOCS2K and C4H8NCS2NH4 in dichloromethane at room temperature yielded the seven coordinated ethyldithiocarbonate thiocarbamoyl‐molybdenum complex [Mo(CO)2(η2‐S2COEt)(η2‐SCNMe2)(PPh3)] 2 , and the dithiocarbamate thiocarbamoyl‐molybdenum complex [Mo(CO)2(η2‐S2CNC4H8)(η2‐SCNMe2)(PPh3)] 3 . The geometry around the metal atom of compounds 2 and 3 are capped octahedrons as revealed by X‐ray diffraction analyses. The thiocarbamoyl and ethyldithiocarbonate or pyrrolidinyldithiocarbamate ligands coordinate to the molybdenum metal center through the carbon and sulfur and two sulfur atoms, respectively. Structure parameters, NMR, IR and Mass spectra are in agreement with the crystal chemistry of the two compounds. 相似文献